Highly efficient catalyst promises easier pathway to hydrogen economy

Highly efficient catalyst promises easier pathway to hydrogen economy

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Hydrogen could be the ideal fuel: Whether used to make electricity in a fuel cell or burned to make heat, the only byproduct is water; there is no climate-altering carbon dioxide. Like gasoline, hydrogen could also be used to store energy. “In the hydrogen evolution reaction, the whole game is coming up with inexpensive alternatives to platinum and the other noble metals,” said Song Jin, a professor of chemistry at the University of Wisconsin-Madison. In the online edition of Nature Materials, Jin’s research team reported a hydrogen-making catalyst containing phosphorus and sulfur — both common elements — and cobalt, a metal that is 1,000 times cheaper than platinum. The new catalyst is almost as efficient as platinum and likely shows the highest catalytic performance among the non-noble metal catalysts reported so far.

The advance emerges from a long line of research in Jin’s lab that has focused on the use of iron pyrite (fool’s gold) and other inexpensive, abundant materials for energy transformation. Jin and his students Miguel Cabán- Acevedo and Michael Stone discovered the new high-performance catalyst by replacing iron to make cobalt pyrite, and then added phosphorus. According to Jin, the new catalyst can also work with the energy from sunlight. “We have demonstrated a proof-of-concept device for using this cobalt catalyst and solar energy to drive hydrogen generation, which also has the best reported efficiency for systems that rely only on inexpensive catalysts and materials to convert directly from sunlight to hydrogen.