Inspired by naturally occurring processes, a team of Boston College chemists used a multi-catalyst system to convert carbon dioxide to methanol at the lowest temperatures reported with high activity and selectivity, the researchers reported in a recent online edition of the journal Chem. The team’s discovery was made possible by installing multiple catalysts in a single system constructed within a sponge-like porous crystalline material known as a metal-organic framework, said Boston College Associate Professors of Chemistry Jeffery Byers and Frank Tsung, lead authors of the report.
Held in place by the sponge, the separate catalysts work in harmony. Without isolation of the catalytically active species in this way, the reaction did not proceed and no product was obtained, they reported.
The team drew its inspiration from the biological machinery in cells, which use multicomponent chemical reactions with great efficiency, Tsung said.
The team employed catalyst separation through host-guest chemistry – where a “guest” molecule is encapsulated in a “host” material to form a new chemical compound – in order to convert carbon dioxide to methanol. The approach, inspired by the multicomponent catalytic transformations in nature, converted a greenhouse gas to a renewable fuel while avoiding high catalytic demand on a single species.
Positioning multiple transition metal complex catalysts at the right position in a system is critical to the reaction turning over. At the same time, encapsulating these catalysts allowed for recyclability in the multicomponent catalytic system, said a researcher.
These properties make the multicomponent catalyst construct more industrially relevant, which may pave the way for a carbon-neutral fuel economy, the researchers said.
In addition to achieving site isolation by encapsulating the catalysts, which led to catalyst activity and recyclability, the team discovered an autocatalytic feature of the catalyst that enabled the reaction to be run without the need for large amounts of additives. Most previous reports for similar reactions use large amounts of additives, but the team’s approach avoids this necessity.
